I don't know exactly how your uni blocks it, but it's probably on the server/router level. When you try and access the site their server redirects the request to a "site blocked" style page. There's not a lot you can do about it except see if you can access it through a proxy.
As for doing it on your own PC, if you have a firewall running there's probably an option to block certain sites, or possibly theres other ways to do it depending on your OS.
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